Quantum correlations encoded in photonic Laguerre-Gaussian modes were shown to be related to the Gouy-phase shifts [Kawase et al., Phys. Rev. Lett. 101, 050501 (2008)], allowing for a nondestructive manipulation of photonic quantum states. In this work, we exploit the relation between phase-space correlations of biphotons produced by spontaneously parametric down-conversion (SPDC) as encoded in the logarithmic negativity (LN) and the Gouy phase as they are diffracted through an asymmetrical double-slit setup. Using an analytical approach based on a double-Gaussian approximation for type-I SPDC biphotons, we show that measurements of Gouy-phase differences provide information on their phase-space entanglement variation, governed by the physical parameters of the experiment and expressed by the LN via covariance matrix elements.